antioxidants and UV stabilizers for polymers
Polymers in this section include r-PVC, f-PVC, POM, PA, PC, PBT, PET, PMMA, ABS, PS, UPES, PU flexible foam, PU micro-cellular foam, TPU, elastomers, TPE and synthetic rubber.
Antioxidants are used for anti-aging, and vitamin has anti-oxidation functions. when it comes to industry, certain antioxidants work for the same purpose. the antioxidant as used to improve polymers’ high-temperature also long-term stability. Except for the heat, products are exposed to light in most cases, no matter its direct sunlight or light from the lamp. Thus UV protection for polymers is vital, otherwise, the products could crack, yellowing, and delamination due to UV light degradation. UV stabilizers contain two groups, the first is Ultraviolet Light Absorbers, also known as UVA or UV absorbers, the second group is Hindered Amine Light Stabilizers which are known as HALS or light stabilizers. They are used individually or as blends. UV absorber filters harmful UV light and helps prevent color change and delamination of coatings, adhesives, and sealants. Light Stabilizers trap free radicals once they are formed and are effective in retaining surface properties such as gloss and preventing cracking and chalking of paints. The combination of these two families is highly synergistic.
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Table 1 Features of antioxidants and UV stabilizers for polymers
Category | Product Name | MW | MR | Features |
antioxidant | 168 | 647 | 183 -186 | Hydrolytically stable phosphite, maintains color properties |
1010 | 1178 | 110 – 125 | High molecular weight, phenolic antioxidant (AO); extends long-term thermal stability | |
1024 | 553 | 221 – 232 | High performance phenolic AO and metal deactivator | |
1035 | 643 | 63 – 78 | Phenolic AO for cross-linked or carbon black containing systems | |
1076 | 531 | 50 – 55 | Highly compatible, low-color phenolic AO | |
1098 | 637 | 156 -161 | Low color phenolic AO, excellent compatibility with PA | |
1135 | 390 | < -30 | Liquid phenolic AO, specifically for PUR | |
1520 | 425 | 12-15 | Synergistic, multifunctional AO for elastomers and TPE | |
245 | 586.8 | 76 – 79 | Phenolic AO, excellent performance in engineering polymers | |
3114 | 784 | 218 – 223 | Non-discoloring phenolic AO; high extraction resistance | |
5057 | NA | NA | Liquid aromatic amine for processing and LTTS | |
B215 | NA | NA | Synergistic phenol/phosphite blend, medium phosphite content for a balanced processing and LTT stability | |
B225 | NA | NA | Synergistic phenol/phosphite blend, low phosphite content | |
B900 | NA | NA | Synergistic phenol/phosphite blend, high phosphite content | |
dltdp | 515 | 39 – 41 | Synergist extending the LTTS of phenolic AOs | |
dstdp | 683 | 64 – 67 | Synergist extending the LTTS of phenolic AOs | |
UV
absorber |
UV P | 225 | 128 – 132 | Benzotriazole for a wide array of substrates |
UV 213 | NA | -40 | Liquid benzotriazole | |
UV 234 | 448 | 137 – 141 | Benzotriazole with low volatility | |
UV 312 | 312 | 124 – 127 | Oxanilide with low initial color | |
UV 326 | 316 | 138 – 141 | Benzotriazole with enhanced absorption of long-wave UV radiation | |
UV 329 | 323 | 103 – 105 | Benzotriazole | |
UV 360 | 659 | 195 | Benzotriazole with very low volatility | |
UV 531 | 326 | 47 – 49 | Benzophenone | |
UV 571 | 394 | -56 | Liquid benzotriazole | |
UV 1577 | 425 | 148 | Hydroxyphenyltriazine with high performance and low volatility | |
light stabilizer | HALS 622 | 3100 -4000 | 50 – 70 | High molecular weight HALS with excellent color, low basicity |
HALS 765 | 508 | NA | Liquid, low molecular weight HALS | |
HALS 770 | 481 | 81 – 85 | Low molecular HALS, especially for automotive applications | |
HALS 783 | NA | NA | Synergistic blend of high molecular weight HALS | |
HALS 791 | NA | NA | Synergistic blend of high and low molecular weight HALS | |
HALS 944 | 2000 -3100 | 100 – 135 | High molecular weight HALS |
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